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Low-Cost Upscaling Compatibility of Five Different ITO-Free Architectures for Polymer Solar Cells

Identifieur interne : 000948 ( Main/Repository ); précédent : 000947; suivant : 000949

Low-Cost Upscaling Compatibility of Five Different ITO-Free Architectures for Polymer Solar Cells

Auteurs : RBID : Pascal:14-0038918

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English descriptors

Abstract

Five different indium-tin-oxide free (ITO-free) polymer solar cell architectures provided by four participating research institutions that all presented a laboratory cell performance sufficient for use in mobile and information and communication technology (ICT) were evaluated based on photovoltaic performance and lifetime tests according to the ISOS protocols. The comparison of the different device architectures was performed using the same active material (P3HT: PCBM) and tested against an ITO-based reference device. The active area was 1 cm2 and rigid glass or flexible polyester substrates were employed. The performance results were corroborated by use of a round robin methodology between the four participating laboratories (DTU/DK, ECN/NL, Frauenhofer ISE/DE, and the Holst Centre/NL), while the lifetime testing experiments were carried out in only one location (DTU). Five different lifetime testing experiments were carried out for a minimum of 1000 h: (1) shelf life (according to ISOS-D-1); (2-3) stability under continuous 1 sun illumination (1000 Wm-2, AM1.5G) at low (37 ± 3°C) and high (80 ± 5°C) temperatures (according to ISOS-L-1 and ISOS-L-2); (4) stability under continuous low-light conditions at 0.1 sun (100 Wm-2, AM1.5G, 32°C) (according to ISOS-LL); (5) continuous illumination (670 Wm-2, AM1.5G) at high temperature (65°C) and high humidity (50% RH) (according to ISOS-L-3). Finally, the upscaling compatibility of these device architectures based on the device photovoltaic behavior, stability and scalability were identified and we confirm that an architecture that presents a high score in only one aspect of the solar cell performance is not sufficient to justify an investment in upscaling. Many will require further technical development.

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Pascal:14-0038918

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<div type="abstract" xml:lang="en">Five different indium-tin-oxide free (ITO-free) polymer solar cell architectures provided by four participating research institutions that all presented a laboratory cell performance sufficient for use in mobile and information and communication technology (ICT) were evaluated based on photovoltaic performance and lifetime tests according to the ISOS protocols. The comparison of the different device architectures was performed using the same active material (P3HT: PCBM) and tested against an ITO-based reference device. The active area was 1 cm
<sup>2 </sup>
and rigid glass or flexible polyester substrates were employed. The performance results were corroborated by use of a round robin methodology between the four participating laboratories (DTU/DK, ECN/NL, Frauenhofer ISE/DE, and the Holst Centre/NL), while the lifetime testing experiments were carried out in only one location (DTU). Five different lifetime testing experiments were carried out for a minimum of 1000 h: (1) shelf life (according to ISOS-D-1); (2-3) stability under continuous 1 sun illumination (1000 Wm
<sup>-2</sup>
, AM1.5G) at low (37 ± 3°C) and high (80 ± 5°C) temperatures (according to ISOS-L-1 and ISOS-L-2); (4) stability under continuous low-light conditions at 0.1 sun (100 Wm
<sup>-2</sup>
, AM1.5G, 32°C) (according to ISOS-LL); (5) continuous illumination (670 Wm
<sup>-2</sup>
, AM1.5G) at high temperature (65°C) and high humidity (50% RH) (according to ISOS-L-3). Finally, the upscaling compatibility of these device architectures based on the device photovoltaic behavior, stability and scalability were identified and we confirm that an architecture that presents a high score in only one aspect of the solar cell performance is not sufficient to justify an investment in upscaling. Many will require further technical development.</div>
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<fC01 i1="01" l="ENG">
<s0>Five different indium-tin-oxide free (ITO-free) polymer solar cell architectures provided by four participating research institutions that all presented a laboratory cell performance sufficient for use in mobile and information and communication technology (ICT) were evaluated based on photovoltaic performance and lifetime tests according to the ISOS protocols. The comparison of the different device architectures was performed using the same active material (P3HT: PCBM) and tested against an ITO-based reference device. The active area was 1 cm
<sup>2 </sup>
and rigid glass or flexible polyester substrates were employed. The performance results were corroborated by use of a round robin methodology between the four participating laboratories (DTU/DK, ECN/NL, Frauenhofer ISE/DE, and the Holst Centre/NL), while the lifetime testing experiments were carried out in only one location (DTU). Five different lifetime testing experiments were carried out for a minimum of 1000 h: (1) shelf life (according to ISOS-D-1); (2-3) stability under continuous 1 sun illumination (1000 Wm
<sup>-2</sup>
, AM1.5G) at low (37 ± 3°C) and high (80 ± 5°C) temperatures (according to ISOS-L-1 and ISOS-L-2); (4) stability under continuous low-light conditions at 0.1 sun (100 Wm
<sup>-2</sup>
, AM1.5G, 32°C) (according to ISOS-LL); (5) continuous illumination (670 Wm
<sup>-2</sup>
, AM1.5G) at high temperature (65°C) and high humidity (50% RH) (according to ISOS-L-3). Finally, the upscaling compatibility of these device architectures based on the device photovoltaic behavior, stability and scalability were identified and we confirm that an architecture that presents a high score in only one aspect of the solar cell performance is not sufficient to justify an investment in upscaling. Many will require further technical development.</s0>
</fC01>
<fC02 i1="01" i2="X">
<s0>001D10A08</s0>
</fC02>
<fC02 i1="02" i2="X">
<s0>001D06C02D1</s0>
</fC02>
<fC02 i1="03" i2="X">
<s0>230</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE">
<s0>Cellule solaire organique</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG">
<s0>Organic solar cells</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE">
<s0>Composé du fullerène</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG">
<s0>Fullerene compounds</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE">
<s0>Styrènesulfonate polymère</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG">
<s0>Styrenesulfonate polymer</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA">
<s0>Estireno sulfonato polímero</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE">
<s0>Ethylène téréphtalate polymère</s0>
<s2>NK</s2>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Ethylene terephthalate polymer</s0>
<s2>NK</s2>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Etileno tereftalato polímero</s0>
<s2>NK</s2>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE">
<s0>Evaluation performance</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Performance evaluation</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA">
<s0>Evaluación prestación</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Mode empilement</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Stacking sequence</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Modo apilamiento</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Relation fabrication propriété</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Fabrication property relation</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Relación fabricación propiedad</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Verre</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Glass</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Vidrio</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Durabilité</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Durability</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Durabilidad</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Vieillissement accéléré</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Artificial ageing</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Envejecimiento acelerado</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Stabilité photochimique</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Photochemical stability</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Estabilidad fotoquímica</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Stabilité thermique</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Thermal stability</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Estabilidad térmica</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Action humidité</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Humidity effect</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Acción humedad</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Norme essai</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Test standard</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Norma ensayo</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Essai interlaboratoire</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG">
<s0>Round robin test</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA">
<s0>Essayo interlaboratorio</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Etude expérimentale</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Experimental study</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Estudio experimental</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>Polymère aromatique</s0>
<s5>31</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG">
<s0>Aromatic polymer</s0>
<s5>31</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA">
<s0>Polímero aromático</s0>
<s5>31</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>Polymère conducteur</s0>
<s5>32</s5>
</fC03>
<fC03 i1="18" i2="3" l="ENG">
<s0>Conducting polymers</s0>
<s5>32</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE">
<s0>Thiophène dérivé polymère</s0>
<s2>NK</s2>
<s5>33</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG">
<s0>Thiophene derivative polymer</s0>
<s2>NK</s2>
<s5>33</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA">
<s0>Tiofeno derivado polímero</s0>
<s2>NK</s2>
<s5>33</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE">
<s0>Polyélectrolyte</s0>
<s5>34</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG">
<s0>Polyelectrolyte</s0>
<s5>34</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA">
<s0>Polielectrolito</s0>
<s5>34</s5>
</fC03>
<fC03 i1="21" i2="X" l="FRE">
<s0>Ester polymère</s0>
<s2>NK</s2>
<s5>35</s5>
</fC03>
<fC03 i1="21" i2="X" l="ENG">
<s0>Ester polymer</s0>
<s2>NK</s2>
<s5>35</s5>
</fC03>
<fC03 i1="21" i2="X" l="SPA">
<s0>Ester polímero</s0>
<s2>NK</s2>
<s5>35</s5>
</fC03>
<fC03 i1="22" i2="X" l="FRE">
<s0>Dégradation photochimique</s0>
<s5>37</s5>
</fC03>
<fC03 i1="22" i2="X" l="ENG">
<s0>Photochemical degradation</s0>
<s5>37</s5>
</fC03>
<fC03 i1="22" i2="X" l="SPA">
<s0>Degradación fotoquímica</s0>
<s5>37</s5>
</fC03>
<fC03 i1="23" i2="X" l="FRE">
<s0>Vieillissement thermique</s0>
<s5>38</s5>
</fC03>
<fC03 i1="23" i2="X" l="ENG">
<s0>Thermal ageing</s0>
<s5>38</s5>
</fC03>
<fC03 i1="23" i2="X" l="SPA">
<s0>Envejecimiento térmico</s0>
<s5>38</s5>
</fC03>
<fC03 i1="24" i2="X" l="FRE">
<s0>Propriété thermique</s0>
<s5>39</s5>
</fC03>
<fC03 i1="24" i2="X" l="ENG">
<s0>Thermal properties</s0>
<s5>39</s5>
</fC03>
<fC03 i1="24" i2="X" l="SPA">
<s0>Propiedad térmica</s0>
<s5>39</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE">
<s0>Thiophène(3-hexyl) polymère</s0>
<s4>INC</s4>
<s5>41</s5>
</fC03>
<fC03 i1="26" i2="X" l="FRE">
<s0>Ethylènedioxythiophène polymère</s0>
<s4>INC</s4>
<s5>42</s5>
</fC03>
<fC03 i1="27" i2="X" l="FRE">
<s0>Vieillissement photochimique</s0>
<s4>INC</s4>
<s5>43</s5>
</fC03>
<fC03 i1="28" i2="X" l="FRE">
<s0>Vieillissement hygrothermique</s0>
<s4>INC</s4>
<s5>44</s5>
</fC03>
<fN21>
<s1>041</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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